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In this study, a novel task-specific ionic liquid functionalized gold nanoparticle (TSIL-GNP) was successfully prepared and applied in the recognition of amino acids. Particularly, the surface of GNP was modified with the ionic liquid containing carbamido and ester group via thiol, which was characterized by Fourier transform infrared spectroscopy (FTIR) and transmission electron microscopy (TEM). The stability of this material in aqueous solution improves apparently and can remain unchanged for more than three months. The effect of pH was also discussed in this study. Attractive ionic interaction would effectively weaken intensity of the covalent coupling between the metal ion and the functional groups of amino acids. Thus, TSIL-GNP was successfully applied to recognizing serine, aspartic acid, lysine, arginine, and histidine in the presence of Cu2+ through distinctive color changes. Suspension would be generated once a spot of cysteine was added into the GNPs solution. Results indicated that it had a good linear relationship between extinction coefficients and concentration of amino acids in a wide range of 10−3–10−6 M. Moreover, the proposed strategy was successfully used to analyze the histidine in urinary samples. In brief, TSIL-GNP is a suitable substrate for discrimination of five amino acids in a rapid and simple way without sophisticated instruments. 相似文献
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A discrete fractional logistic map is proposed in the left Caputo discrete delta’s sense. The new model holds discrete memory. The bifurcation diagrams are given and the chaotic behaviors are numerically illustrated. 相似文献
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In emergency management, it is important to arrange the medical resources according to emergency needs. This paper proposes a multi-criteria decision analysis model that combines grey theory and multi-criteria decision making theory to assess the current medical resource situation, find satisfactory solutions, and help the emergency decision makers to take appropriate responses in a timely manner. In addition, the best alternative is identified by the global optimal solution which can provide a theoretical guidance for decision makers to optimize the allocation of medical resources. To validate the proposed model, this paper conducts a case study of medical service assessment in provinces of East China. The results demonstrate that the proposed model can provide objective and comprehensive assessment of medical resources. 相似文献